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Published 17:36 16 Feb 2022 GMT
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"He was hijacked, they took his car and shot him in the head," his brother Lewis told BBC Sport.
His friend Innocent Chikoya - who played with him at Fire Batteries FC and African Wanderers in South Africa - labelled Yohane as a 'clever and intelligent footballer' who was a 'leader, disciplined and dedicated'.
"He wasn't a friend, he was a brother, and we have lost him in bad circumstances," Chikoya told BBC Sport.
"He was clever, an intelligent footballer, he had ways of getting things done. He was a leader, disciplined and dedicated.
"I will be collecting his body from the funeral parlour on Thursday and will be taking him home."
Edelbert Dinha, who was in the Zimbabwe squad at the 2006 Nations Cup and was a close friend to Yohane, revealed that he had been attempting to contact him over the weekend.
"We tried calling him from Saturday up to Monday, and we couldn't reach him," Dinha told BBC Sport.
"Then I went to the police station.
"Charles was a quiet person, always smiling, he never argued with anyone. He was coaching Leruma United FC in the ABC Motsepe League."
Yohane is the second member of the 2004 Zimbabwe Africa Cup of Nations squad to die after striker Adam Ndlovu died in December 2012. Related links:World Cup 2026 prize money: The staggering amount the winners can earn revealed
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